The whole point of exporting the database in raw form is so that you can use your own code to order it however you want.
If you're good with Excel (or perhaps Access), I'm sure you could work up a script that allowed you to organize the CSV data in playlist order.
My question is: Why would you WANT to? Emplode already shows all your files in playlist order. If someone is exporting the database to CSV, it's usually because they want it in some format that Emplode won't show them.
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Tony Fabris