At the moment, there isn't a way for Hijack to do perform an "Insert" or "append" (this is the player's nomenclature for the "cue" you requested) via serial commands (which is how Hijack plays tracks).

However, the specific feature you asked for has been requested of the development team (the ability to insert or append from serial commands). I do not know if/when this feature will appear.
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Tony Fabris