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Schools don't want old PC's any more. They've all got massive IT budgets these days and have all new whizzy kit

I don't know the situation in the UK, but that's definitely not true here. At work, we just got done giving a dozen or so old PCs to the local school system. And about a year ago, we gave a bunch of decrepit PCs to Duke University, which is probably one of the wealthier universities in the US.
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Bitt Faulk